Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion.
نویسندگان
چکیده
The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k=40 s(-1) at 303 K).
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 شماره
صفحات -
تاریخ انتشار 2007